Cryogenic distillation comprising vacuum insulation panel

ABSTRACT

A cryogenic installation unit comprises at least one item of equipment to be thermally insulated, a structure for containing the at least one item of equipment, a main insulation contained in the structure and, associated with this main insulation, a secondary insulation of lower thermal conductivity than the main insulation, said secondary insulation consisting of a vacuum insulation panel.

CROSS REFERENCE TO RELATED APPLICATIONS

This application is a continuation of application Ser. No. 12/303,796, now U.S. Pat. No. 8,528,362, filed Dec. 8, 2008, which is a §371 of International PCT Application PCT/EP2007/055980, filed Jun. 15, 2007, which claimed the benefit of FR 06/52671, filed Jun. 27, 2006, all of which are incorporated by reference herein in their entireties.

BACKGROUND

1. Field of the Invention

The object of the invention is to optimize the thermal insulation of equipment, in particular cryogenic equipment, by the use of several insulation technologies on one and the same item(s) of equipment or on one and the same set of equipment.

2. Related Art

For cryogenic applications, the insulation technology offering at the present time the best compromise is often the cold box, as described in “Tieftemperaturtechnik [Cryogenics]”, 1985, pages 490-495.

A cold box is a structure (which is generally parallelepipedal) containing the equipment to be insulated and filled with an insulation, generally in powder form (one of the insulations most frequently used in cryogenics is perlite). This insulation generally fills the entire space between the items of equipment and the entire space between the equipment and the structure.

The main functions of the structure are:

-   -   to support the insulation; and     -   to partly support the equipment.

The main functions of the insulation are:

-   -   to limit the heat losses between the items of equipment and the         outside; and     -   to limit heat exchange between the items of equipment.

When designing a cold box, the insulation technology chosen is a compromise between several constraints:

-   -   safety (compatibility of the insulation with the products to be         insulated, etc.) and the environment (toxicity of the         insulation, end-of-life recycling, etc.);     -   the absence or slight presence of frosting, which may accelerate         wear of the equipment and pose safety problems;     -   accessibility to the equipment;     -   investment cost; and     -   loss of energy, divided into:         -   specified heat loss to the outside         -   specified heat exchange between the various items of             equipment in the box.

One of the advantages of a cold box is that it insulates a set of equipment overall (within the context of this patent, the term “equipment” includes all items to be insulated, including any pipework) instead of having to insulate the items of equipment one by one, hence making a substantial saving in time and labour as regards investment cost.

Among the drawbacks, the following may be noted:

-   -   the need to construct an external structure for supporting and         containing the insulation. This structure is particularly bulky         and expensive. Its cost is, to a certain extent, proportional to         its volume, the latter depending in particular on:         -   the size of the equipment,         -   the space required to fit the equipment and         -   the necessary thickness of insulation;     -   the accessibility of the equipment, which is restricted in         operation (in particular when an insulation in powder form is         used). This is because, to gain access to an individual item of         equipment, it is often necessary to drain off a large amount of         insulation.

SUMMARY OF THE INVENTION

The object of the invention is to optimize the thermal insulation of the equipment by keeping the principle of the box but combining several insulation technologies therewith.

The invention therefore consists of a box comprising:

-   -   items of equipment to be thermally insulated with respect to the         outside and with respect to other items of equipment;     -   a structure containing the items of equipment and their         insulations, the function of which is to support the insulation         and partly support the items of equipment;     -   a main insulation; and     -   secondary insulations associated with this main insulation.

An insulation is considered to be secondary if its volume is less than that of the main insulation.

These secondary insulations make it possible, by local action, to lessen the drawbacks of the box, while keeping its advantages and by meeting the design constraints.

Thus, the local use of a secondary insulation of lower thermal conductivity than the main insulation makes it possible:

-   -   to reduce the space required to fit the equipment;     -   to reduce the thickness of insulation; and     -   to reduce the size of the structure for the same heat loss, and         therefore to reduce the investment cost.

This secondary insulation must meet the general insulation design constraints.

Thus, the local use of a secondary insulation, which is easier to remove, will allow easier and quicker access to certain items of equipment, for example those requiring frequent maintenance.

According to one aspect, the subject of the invention is a cryogenic distillation installation comprising:

-   -   at least one item of equipment to be thermally insulated;     -   a structure for containing at least one item of equipment;     -   a main insulation contained in the structure, the main         insulation being a solid insulation;     -   associated with this main insulation, a secondary insulation of         lower thermal conductivity than the main insulation,         and characterized in that the second insulation is in the form         of at least one vacuum insulation panel.

The vacuum insulation panel is made of an insulating material placed in an impervious case. Before closing the case, the insulation is subjected to a reduced pressure, for creating a vacuum therein.

The materials used comprise glass fibre, perlite, polystyrene, etc.

The closed case may be formed from flat or curved plates.

According to other optional aspects:

-   -   the thermal conductivity of the secondary insulation is at least         twice as low as that of the main insulation;     -   at least one item of equipment to be insulated contains, in         operation, at least one fluid at a cryogenic temperature;     -   the main insulation is in powder form, for example perlite         powder;     -   the secondary insulation is displaced over an opening in the         outer case;     -   the secondary insulation is put into place on the equipment to         be insulated;     -   the secondary insulation is placed on the outer and/or inner         case of the structure;     -   the structure is a cold box;     -   the secondary insulation is incorporated into the outer or inner         case of the structure and/or on the equipment, in particular by         bonding or colaminating;     -   the secondary insulation is between the equipment to be         insulated and the outer case of the structure;     -   the equipment to be insulated is at a distance x from the         closest point on the structure, which constitutes a first point,         and a second point on the structure is separated from the         closest equipment to be insulated by a distance nx, n being         greater than 5, or even 10, and the space between the second         point and the equipment not comprising a vacuum insulation         panel;     -   the secondary insulation is on the outside of the outer case of         the structure;     -   the secondary insulation is located on at least one projecting         part of the structure of the cold box, for example on braces, or         beams or angle sections;     -   the secondary insulation is preferably just installed on at         least one region of the equipment lying at a distance from the         structure below a given threshold and/or on at least one region         of the structure lying at a distance from the equipment below a         given threshold;     -   the secondary insulation is installed on all the regions of the         equipment lying at a distance from the structure below a given         threshold and/or on the entire region of the structure lying at         a distance from the equipment below a given threshold;     -   the entire region of all the equipment lying at a distance from         the closest point on the structure below a given threshold         and/or on the entire region of the structure lying at a distance         on the closest point on the equipment below a given threshold is         insulated by means of a secondary insulation;     -   the equipment is a storage tank, a phase separator, a column, a         heat exchanger, pipework, a pump, a valve or a turbine;     -   the equipment is located in a region inside the structure, one         side of this region being closed off by at least one vacuum         insulation panel and the region being insulated from the rest of         the inside of the structure by a barrier;     -   the region where the equipment is located contains at least one         bag containing insulation in loose form;     -   the structure contains a cryogenic distillation unit, preferably         an air distillation unit;     -   the secondary insulation is installed on at least one region of         a structure which is in an operating state at an average         temperature below or above a given threshold and/or which is         exposed to sunlight to a greater or lesser extent than the other         regions of the structure;     -   the thickness of the secondary insulation is higher in at least         one region of the structure which is, in the operating state, at         an average temperature below or above a given threshold and/or         is exposed to sunlight to a greater or lesser extent than other         regions of the structure; and     -   the secondary insulation consists entirely or partly of         non-flammable material.

BRIEF DESCRIPTION OF THE FIGURES

The invention will be described in greater detail with reference to the drawings, FIG. 1 of which represents the prior art, FIGS. 2 to 4 represent, schematically, an installation according to the invention seen in cross section from above, and FIGS. 5 to 9 represent part of an installation according to the invention seen in cross section from the side.

DETAILED DESCRIPTION OF THE INVENTION

According to the prior art, a “cold box” installation contains the items of equipment operating at the lowest temperatures of an air separation unit, in particular one or more columns, pipework, one or more heat exchangers, including one that may act as subcoolers, possibly at least one turbine and possibly at least one pump. FIG. 1 shows a cuboid structure 1 of square section, containing a column 2, for example air separation double column, and various items of equipment to be insulated, such as turbines, heat exchangers, pipework, etc . . . 6A to 6J. The structure 1 may alternatively be of circular cross section. The column and the pipework are surrounded with insulation 3, for example perlite.

According to the invention, in FIG. 2, at least some of the items of equipment having part of their surface lying at a distance below a given threshold are covered on at least this part of the surface with a secondary insulation 5 having a lower thermal conductivity than the main insulation 3 that fills the internal space of the structure 1. In particular, it should be noted that part of the surface of the column 2 and part of the surfaces of the various items of equipment to be insulated 6A, 6B and 6E are covered with secondary insulation 5 in the form of a vacuum insulation panel.

It is possible for surfaces positioned at a distance below the threshold not to be covered for cost reasons or if the item of equipment has a low thermal mass or is used only occasionally. The item of equipment 6G is a vertical pipe which has a first right-angle bend so as to pass into the horizontal (and away from the column) and a second right-angle bend in order to continue in the vertical. Alternatively, as may be seen in FIG. 3, the covering may be on the inner case of the structure 1 in those parts of the surface of the latter that are located at a distance below a threshold from an item of equipment contained in the structure 1. Thus, the surfaces of the inner case facing the items of equipment 2, 6A, 6C, 6E and at a distance below a threshold from them are covered with a sheet of secondary insulation 5 in the form of a vacuum insulation panel, having a lower thermal conductivity than the main insulation 3 that fills the internal space of the structure 1.

It is possible for the surfaces positioned at a distance below the threshold not to be covered for cost reasons or if the item of equipment has a low thermal mass or is used only occasionally.

A particular benefit of a secondary insulation of lower thermal conductivity applied locally (as indicated in FIG. 2) in a cold box should be noted, as opposed to, for example, a cryogenic liquid storage tank in which the insulation thicknesses between the cryogenic fluids and the outside are much more constant.

This is because (cf. FIG. 1), in a cold box the insulation thicknesses between the cryogenic fluids and the outside vary greatly. Thus, certain items of equipment are separated from the structure by a large thickness of insulation, whereas others are much closer to the structure and the cryogenic fluids that they contain are practically also as cold.

For a separation unit, there may be components at cryogenic temperature 30 cm from the structure, whereas, for other regions of the structure, the closest component is 1.5 m therefrom. Thus, the ratio of the distance of the closest component from a point on the structure to the distance of the closest component from another point on the structure may range from ½ to 1/10.

When storing a cryogenic fluid, the insulation is generally provided by a double-walled jacket filled with insulation, the fluid, at a given temperature, thus being thermally insulated from the outside by an almost constant thickness of insulation. In FIG. 4, the structure 1 of the installation is a box of square external structure. Inside the box, there is a main item of equipment 2 to be insulated, this being cylindrical of diameter D. This item of equipment could be a column, for example an air distillation column or a storage tank, such as a cryogenic liquid storage tank. The minimum insulation distance emin1 determines the size of the structure 1. The space between the equipment and the structure is filled with a main insulation 3, for example perlite. The outer surfaces of the structure 1 at a distance below the threshold e(α) are covered with a secondary insulation 5 in the form of a vacuum insulation panel. Thus, three of the surfaces are partly covered with the insulation 5, whereas the fourth, which is further away, is not.

It is obviously possible to combine the three types of insulation shown in FIGS. 2, 3 and 4 by covering, with secondary insulation 5 in the form of a vacuum insulation panel, at least one item of equipment to be insulated and/or the inside of the structure 1 and/or the outside thereof. It is also conceivable to position the secondary insulation 5 between the item of equipment to be insulated and the structure, said insulation being surrounded by the main insulation 3.

FIG. 4 illustrates the surface of the structure as if it were flat. In fact, the structure is typically made up of sheet metal plates strengthened by vertical posts, horizontal beams and braces placed diagonally, it being possible for these to be inside and/or outside of the structure.

FIG. 5 illustrates an installation comprising a structure 1 having an inner case 11 with a horizontal beam 7 of rectangular cross section on the outside of the case 11, forming a projection. The secondary insulation 5, in the form of a vacuum insulation panel, may be placed in a cylindrical plate on the vertical pipework 6, part of the surface of which lies at a distance below a given threshold from the beam 7. Perlite 3 also insulates the space between the equipment 6 and the case 11.

In FIG. 6, the horizontal beam 7 is located inside the structure and is insulated by perlite 3 and a sheet of secondary insulation 5 in the form of a vacuum insulation panel, interposed between the beam 7 and the equipment 6.

In FIG. 7, a sheet of insulation 5 in the form of a vacuum insulation panel is placed inside the case 11 and the horizontal beam 7 is located outside of the structure. Perlite 3 and a sheet of secondary insulation 5 are interposed between the beam 7 and the equipment 6.

In FIG. 8, the beam 7 is located on the inside of the structure and is insulated by perlite 3 (to be added to the figure) between the beam 7 and equipment 6. However, the beam is also covered with secondary insulation 5 in the form of a vacuum insulation panel over part of its surface located at a distance below a given threshold from the surface of the equipment 6.

The addition of a secondary insulation 5, in the form of a vacuum insulation panel, to the outer wall of the structure 1 makes it possible to reduce emin1 and therefore the cross section of the structure 1.

Let L be the length of the secondary insulation 5 in sheet form that must be added in order to keep the heat losses from the box to the outside constant. L may be estimated in the following manner:

-   -   let emin1 be the minimum distance between the main item of         equipment 2 and the closest point on the structure 1;     -   let emin1 _((main insulation)) be the minimum distance of the         insulation, set by calculation, between the main item of         equipment 2 and the closest point on the structure 1 for         specified constraints (heat losses with the outside, etc.) when         the main insulation is used;     -   let emin1 _((secondary insulation)) be the minimum distance of         the insulation, set by calculation, between the main item of         equipment 2 and the closest point on the structure 1 for         specified constraints (heat losses with the outside, etc.) when         the secondary insulation is used;     -   let D be the diameter of the equipment 2;     -   let α be the angle shown in FIG. 4 and let e(α) be the distance         between the main item of equipment 2 and the structure 1 for a         given angle α;     -   if emin1=emin1 _((secondary insulation)) when e(α)=emin1         _((main insulation)), then L=D sin α.

The table below gives the reduction in box volume obtained when a secondary insulation 2 to 5 times more effective than the main insulation is used.

Applic- Diameter Minimum Minimum ation Cross (D) of the insulation insulation length (L) sec- Re- main item thickness thickness of the tion duction of (secondary Alpha (main secondary of the in box equipment insulation) (α) insulation) insulation box volume m m rad m m m2 % 4.00 0.50 0.00 0.50 0.00 25.00 Ref- erence 4.00 0.20 0.55 0.50 2.11 19.36 22.56 4.00 0.10 0.64 0.50 2.40 17.64 29.44 4.00 0.25 0.51 0.50 1.94 20.25 19.00

By applying the secondary insulation 5 over a length L of 2 metres, a 20 to 30% reduction in the volume of structure 1 is obtained.

This calculation is approximate as it does not take into account certain form factors in the case of heat losses, but nevertheless it does show that the use of the secondary insulations is highly advantageous.

Preferably, the secondary insulation 5 takes the form of one or more sheets. Several sheets of standard size may be juxtaposed in order to cover the intended surface.

The secondary insulation 5 is formed by a vacuum insulation panel. In particular, the insulation may be a vacuum insulation panel as described in U.S. Pat. No. 4,726,974, U.S. Pat. No. 5,445,857, U.S. Pat. No. 3,894,372 or U.S. Pat. No. 6,335,074. Alternatively, the secondary insulation 5 takes the form of a portion of a cylinder so as to surround part of a cylindrical item of equipment, such as a column, a pipe, a storage tank or a cylindrical structural component (a post, beam or brace). Also alternatively, the secondary insulation 5 may have a U-shape to be placed on a beam, post or brace of square or rectangular cross section.

It is also conceivable to position the secondary insulation 5 according to the exposure to the sun, the south face (in the northern hemisphere) being covered with secondary insulation (or proportionally more secondary insulation 5 than the other faces of the installation). Conversely, to prevent frosting, the thickness of the secondary insulation 5 may be increased on the faces least exposed to sunshine in temperate or cold regions.

It may also be useful to take into account the presence of units close to the installation that operate at high temperature and may thus transfer heat to the installation. The faces of the structure 1 near these units may be covered with insulation 5 in order to allow the installation to be placed closer to other units on the site.

The column 2 may be a single air separation column, an argon column, a mixing column or any other column for separating a gas from air. Likewise, the structure 1 may contain a system of columns and/or several heat exchangers and/or several pipework systems.

In FIG. 9, a valve 15 is positioned near the wall of the case 11. This case 11 has an opening to allow occasional access to the valve 15. In normal use, this opening is closed and sealed off by a vacuum insulation panel 5 attached to the case 11.

The space around the valve may be filled with bagged insulation 13, for example with glass wool, rock wool or perlite. This filling is not necessarily very dense, but it is advantageous to avoid the formation of thermal loops and icing. The spacing between bags 13 may be filled with purge gas and the main insulation 3 (for example perlite) is supported by a barrier 17, which is preferably not impermeable to the purge gas that may be used with the main insulation (in particular when this is in powder form). The perforations allow the dry purge gas to ventilate the space around the valve 15. This configuration allows rapid access to the valve without having to remove the main insulation (in particular when it is in solid powder form) from the entire cold box down to level with the valve.

The vacuum insulation panels 5 are preferably made of a metal having a very low thermal expansion coefficient, for example Ni-36. The thermal expansion coefficient should not exceed 5×10⁻⁵ m/K.

This invention has been described with regard to an air distillation unit. However, the invention obviously applies to other distillation operations or processes operating at low temperature, especially a unit used for the distillation of hydrogen and carbon monoxide.

While the invention has been described in conjunction with specific embodiments thereof, it is evident that many alternatives, modifications, and variations will be apparent to those skilled in the art in light of the foregoing description. Accordingly, it is intended to embrace all such alternatives, modifications, and variations as fall within the spirit and broad scope of the appended claims. The present invention may suitably comprise, consist or consist essentially of the elements disclosed and may be practiced in the absence of an element not disclosed. Furthermore, if there is language referring to order, such as first and second, it should be understood in an exemplary sense and not in a limiting sense. For example, it can be recognized by those skilled in the art that certain steps can be combined into a single step.

The singular forms “a”, “an” and “the” include plural referents, unless the context clearly dictates otherwise.

“Comprising” in a claim is an open transitional term which means the subsequently identified claim elements are a nonexclusive listing (i.e., anything else may be additionally included and remain within the scope of “comprising”). “Comprising” as used herein may be replaced by the more limited transitional terms “consisting essentially of” and “consisting of” unless otherwise indicated herein.

“Providing” in a claim is defined to mean furnishing, supplying, making available, or preparing something. The step may be performed by any actor in the absence of express language in the claim to the contrary a range is expressed, it is to be understood that another embodiment is from the one.

Optional or optionally means that the subsequently described event or circumstances may or may not occur. The description includes instances where the event or circumstance occurs and instances where it does not occur.

Ranges may be expressed herein as from about one particular value, and/or to about another particular value. When such particular value and/or to the other particular value, along with all combinations within said range

All references identified herein are each hereby incorporated by reference into this application in their entireties, as well as for the specific information for which each is cited. 

1-21. (canceled)
 22. Cryogenic distillation apparatus comprising: at least one item of equipment to be thermally insulated, selected from the group consisting of a storage tank, a phase separator, a column, a heat exchanger, pipework, a pump, a valve, a turbine, and combinations thereof; a structure for containing the at least one item of equipment; a main insulation contained in the space between the equipment and the structure, wherein said main insulation comprises a solid perlite insulation; and a secondary insulation having a lower thermal conductivity than the main insulation, wherein said secondary insulation comprises at least one vacuum insulation panel, wherein the secondary insulation is disposed in the cryogenic distillation apparatus such that the secondary insulation is configured to reduce the thermal conductivity between the at least one item of equipment and the atmosphere.
 23. The apparatus according to claim 22, in which the thermal conductivity of said secondary insulation is one half or less than that of said main insulation.
 24. The apparatus according to claim 22, in which said at least one item of equipment to be thermally insulated contains, in operation, at least one fluid at a cryogenic temperature.
 25. The apparatus according to claim 22, in which said secondary insulation is displaced over an opening in said structure.
 26. The apparatus according to claim 22, in which said secondary insulation is installed on the equipment to be insulated.
 27. The apparatus according to claim 22, in which said structure comprises an outer case and an inner case, and wherein said secondary insulation is placed on the outer case, the inner case, or both outer case and inner case of said structure.
 28. The apparatus according to claim 27, in which said secondary insulation is incorporated into the outer case, the inner case of the structure, on said equipment to be thermally insulated, or any combination thereof.
 27. The apparatus according to claim 27, in which said secondary insulation is located between said equipment to be thermally insulated and said outer case of the structure.
 30. The apparatus according to claim 29, in which said equipment to be thermally insulated is at a distance x from the closest point on said structure, which constitutes a first point, and a second point on said structure is separated from the closest equipment to be thermally insulated by a distance nx, n being greater than 2, and the space between the second point and the equipment comprises an absence of the secondary insulation.
 31. The apparatus according to claim 27, in which said secondary insulation is on the outside of said outer case of the structure.
 32. The apparatus according to claim 22, wherein said structure has at least one projecting part, and wherein said secondary insulation is located on said at least one projecting part of the structure.
 32. The apparatus according to claim 32, wherein said at least on projecting part is selected from the group consisting of braces, beams and angle sections.
 34. The apparatus according to claim 22, in which the secondary insulation is only installed on at least one region of the equipment lying at a distance from said structure below a given threshold and/or on at least one region of the structure lying at a distance from the equipment below a given threshold.
 35. The apparatus according to claim 34, in which said secondary insulation is installed on all the regions of the equipment lying at a distance from the structure below a given threshold and/or on the entire region of the structure lying at a distance from the equipment below a given threshold.
 36. The apparatus according to claim 34, in which the entire region of all the equipment lying at a distance from the closest point on the structure below a given threshold and/or on the entire region of the structure lying at a distance on the closest point on the equipment below a given threshold is insulated by means of a secondary insulation.
 37. The apparatus according to claim 22, in which the equipment is located in a region inside the structure, one side of this region being closed of by at least one vacuum insulation panel and the region being insulated from the rest of the inside of the structure by a barrier.
 38. The apparatus according to claim 22, wherein the secondary insulation is disposed on the equipment to be insulated but is not in contact with the structure, wherein the space between the structure and the secondary insulation is filled by the main insulation.
 39. The apparatus according to claim 22, wherein the secondary insulation is disposed on the outer case of the structure, but is not in contact with any equipment, the space between the structure and any equipment being filled by the main insulation.
 40. The apparatus according to claim 22, wherein the secondary insulation is disposed on the inner case of the structure, but is not in contact with any equipment, and the space between the secondary insulation and any equipment being filled by the main insulation.
 41. The apparatus according to claim 22, wherein the secondary insulation is disposed between the equipment and the structure but is not in contact with either thereof, the space between the secondary insulation and the equipment and the space between the secondary insulation and structure being filled by the main insulation. 